The Extended Hipparcos Compilation (XHIP) cross-references the New Hipparcos Reduction (HIP2, Cat. I/311) with relatable data from a broad survey of presently available sources. The resulting collection uniquely assigns 116,096 spectral classifications, 46,392 radial velocities, and 19,097 iron abundances [Fe/H] to Hipparcos stars. Stellar classifications from SIMBAD and indications of multiplicity from either CCDM (Cat. I/274) or WDS (Cat. B/wds) are provided. Parameters for solar encounters and Galactic orbits are calculated for a subset of stars that can be made kinematically complete. Memberships in open clusters and stellar associations are assigned. We also provide stellar ages from The Geneva-Copenhagen survey of the Solar neighbourhood III (Cat. V/130), identifications of exoplanet host stars, and supplemental photometry from 2MASS (Cat. II/246) and SIMBAD.