On the basis of the data observed with the Photoelectric Transit Instrument, of the Beijing Astronomical Observatory during the period from 1980 through 1984, the third preliminary catalogue of stars on right ascension observed with the Photoelectric Transit Instrument (PPCP3) have been compiled. The relations between the residuals V and the magnitude M, and the spectral type S of FK4 stars are discussed. There are 411 stars in this catalogue. The mean precisions of {DELTA}alpha's is +/-2.3ms. Finally systematic corrections of PPCP3-FK4 are given.