ExoMol line lists for phosphine (PH_3_) Virtual Observatory Resource

Authors
  1. Sousa-Silva C.
  2. Al-Refaie A.F.
  3. Tennyson J.
  4. Yurchenko S.N.
  5. Published by
    CDS
Abstract

A comprehensive hot line list is calculated for ^31^PH_3_ in its ground electronic state. This line list, called SAlTY, contains almost 16.8 billion transitions between 7.5 million energy levels and it is suitable for simulating spectra up to temperatures of 1500K. It covers wavelengths longer than 1um and includes all transitions to upper states with energies below hc.18000cm^-1^ and rotational excitation up to J=46. The line list is computed by variational solution of the Schrodinger equation for the rotation-vibration motion employing the nuclear-motion program TROVE. A previously reported ab initio dipole moment surface is used as well as an updated 'spectroscopic' potential energy surface (PES), obtained by refining an existing ab initio surface through least-squares fitting to the experimentally derived energies. Detailed comparisons with other available sources of phosphine transitions confirms SAlTY's accuracy and illustrates the incompleteness of previous experimental and theoretical compilations for temperatures above 300K. Atmospheric models are expected to severely underestimate the abundance of phosphine in disequilibrium environments, and it is predicted that phosphine will be detectable in the upper troposphere of many substellar objects. This list is suitable for modelling atmospheres of many astrophysical environments, namely carbon stars, Y dwarfs, T dwarfs, hot Jupiters and solar system gas giant planets. It is available in full as supplementary data to the article and at www.exomol.com.

Keywords
  1. Astronomical models
  2. Stellar atmospheres
  3. Infrared astronomy
  4. Spectroscopy
  5. Ultraviolet astronomy
Bibliographic source Bibcode
2015MNRAS.446.2337S
See also HTML
https://cdsarc.cds.unistra.fr/viz-bin/cat/J/MNRAS/446/2337
IVOA Identifier IVOID
ivo://CDS.VizieR/J/MNRAS/446/2337

Access

Web browser access HTML
http://vizier.cds.unistra.fr/viz-bin/VizieR-2?-source=J/MNRAS/446/2337
https://vizier.iucaa.in/viz-bin/VizieR-2?-source=J/MNRAS/446/2337
http://vizieridia.saao.ac.za/viz-bin/VizieR-2?-source=J/MNRAS/446/2337
IVOA Table Access TAP
http://tapvizier.cds.unistra.fr/TAPVizieR/tap
Run SQL-like queries with TAP-enabled clients (e.g., TOPCAT).

History

2014-12-01T14:34:55Z
Resource record created
2014-12-01T14:34:55Z
Created
2015-05-02T16:04:51Z
Updated

Contact

Name
CDS support team
Postal Address
CDS, Observatoire de Strasbourg, 11 rue de l'Universite, F-67000 Strasbourg, France
E-Mail
cds-question@unistra.fr