We use ROSAT All Sky Survey broad-band X-ray images and the optical clusters identified from Sloan Digital Sky Survey Data Release 7 to estimate the X-ray luminosities around ~65000 candidate clusters with masses >~10^13^h-1^M_{sun}_ based on an optical to X-ray (OTX) code we develop. We obtain a catalogue with X-ray luminosity for each cluster. This catalogue contains 817 clusters (473 at redshift z<=0.12) with signal-to-noise ratio >3 in X-ray detection. We find about 65% of these X-ray clusters have their most massive member located near the X-ray flux peak; for the rest 35%, the most massive galaxy is separated from the X-ray peak, with the separation following a distribution expected from a Navarro-Frenk-White profile. We investigate a number of correlations between the optical and X-ray properties of these X-ray clusters, and find that the cluster X-ray luminosity is correlated with the stellar mass (luminosity) of the clusters, as well as with the stellar mass (luminosity) of the central galaxy and the mass of the halo, but the scatter in these correlations is large. Comparing the properties of X-ray clusters of similar halo masses but having different X-ray luminosities, we find that massive haloes with masses >~10^14^h^-1^M_{sun}_ contain a larger fraction of red satellite galaxies when they are brighter in X-ray. An opposite trend is found in central galaxies in relative low-mass haloes with masses <~10^14^h^-1^M_{sun}_ where X-ray brighter clusters have smaller fraction of red central galaxies. Clusters with masses >~10^14^h^-1^M_{sun}_ that are strong X-ray emitters contain many more low-mass satellite galaxies than weak X-ray emitters. These results are also confirmed by checking X-ray clusters of similar X-ray luminosities but having different characteristic stellar masses. A cluster catalogue containing the optical properties of member galaxies and the X-ray luminosity is available at http://gax.shao.ac.cn/data/Group.html.