With the goal of investigating the nature and the environment of the faint radio sources (at mJy level), here are presented results of X-ray identifications of Faint Imaging Radio Survey at Twenty centimetres (FIRST) in the 9deg^2^ Bootes field of the National Optical Astronomy Observatory (NOAO) Deep Wide Field Survey (NDWFS), using data from the Chandra XBootes survey. A total of 92 (10 per cent) FIRST radio sources are identified above the X-ray flux limit f_X_)(0.5-7)keV=8x10^-15^erg/s/cm^2^, and 79 optical counterparts are common to both the radio and X-ray sources. Spectroscopic identifications [obtained from the Sloan Digital Sky Survey (SDSS) survey] were available for 22 sources (27 per cent).