We have obtained calcium abundances and radial velocities for 102 red giant branch (RGB) stars in the Leo I dwarf spheroidal galaxy (dSph) and 74 RGB stars in the Leo II dSph using the low-resolution spectrograph (LRIS) on the Keck I 10-m telescope. We report on the calcium abundances [Ca/H] derived from the strengths of the Ca ii triplet absorption lines at 8498, 8542 and 8662{AA} in the stellar spectra using a new empirical Ca II triplet calibration to [Ca/H].