IR spectrum of protonated ovalene (7-C_32_H_15_^+^) Virtual Observatory Resource

Authors
  1. Tsuge M.
  2. Bahou M.
  3. Wu Y.-J.
  4. Allamandola L.
  5. Lee Y.-P.
  6. Published by
    CDS
Abstract

The mid-infrared emission from galactic objects, including reflection nebulae, planetary nebulae, proto-planetary nebulae, molecular clouds, etc, as well as external galaxies, is dominated by the unidentified infrared (UIR) emission bands. Large protonated polycyclic aromatic hydrocarbons (H^+^PAHs) were proposed as possible carriers, but no spectrum of an H^+^PAH has been shown to exactly match the UIR bands. Here, we report the IR spectrum of protonated ovalene (7-C_32_H_15_^+^) measured in a para-hydrogen (p-H_2_) matrix at 3.2K, generated by bombarding a mixture of ovalene and p-H_2_ with electrons during matrix deposition. Spectral assignments were made based on the expected chemistry and on the spectra simulated with the wavenumbers and infrared intensities predicted with the B3PW91/6-311++G(2d,2p) method. The close resemblance of the observed spectral pattern to that of the UIR bands suggests that protonated ovalene may contribute to the UIR emission, particularly from objects that emit Class A spectra, such as the IRIS reflection nebula, NGC 7023.

Keywords
  1. atomic-physics
  2. infrared-astronomy
  3. spectroscopy
Bibliographic source Bibcode
2016ApJ...825...96T
See also HTML
https://cdsarc.cds.unistra.fr/viz-bin/cat/J/ApJ/825/96
IVOA Identifier IVOID
ivo://CDS.VizieR/J/ApJ/825/96
Document Object Identifer DOI
doi:10.26093/cds/vizier.18250096

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http://vizieridia.saao.ac.za/viz-bin/VizieR-2?-source=J/ApJ/825/96
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History

2016-10-11T15:44:44Z
Resource record created
2016-10-11T15:44:44Z
Created
2017-01-23T22:00:00Z
Updated

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