The planetary nebula (PN) population of M33 is studied via multifiber spectroscopy with Hectospec at the MMT. In this paper, we present the spectra of 102 PNe, whereas plasma diagnostic and chemical abundances were performed on the 93 PNe where the necessary diagnostic lines were measured. About 20% of the PNe are compatible with being Type I; the rest of the sample is the progeny of an old disk stellar population, with main sequence masses M<3M_{sun}_ and ages t>0.3Gyr. Our observations do not seem to imply that the metallicity gradient across the M33 disk has flattened considerably with time. We report also the discovery of a PN with Wolf-Rayet features, PN039, belonging the class of late [WC] stars.