We present an analysis of 402 F, G, and K solar neighborhood stars, with accurate estimates of [Fe/H] in the range -1.0 to +0.5dex, aimed at the detection of {alpha}-enhanced stars and at the investigation of their kinematical properties. The analysis is based on the comparison of 571 sets of spectral indices in the Lick/IDS system, coming from four different observational data sets, with synthetic indices computed with solar-scaled abundances and with {alpha}-element enhancement. We use selected combinations of indices to single out {alpha}-enhanced stars without requiring previous knowledge of their main atmospheric parameters. By applying this approach to the total data set, we obtain a list of 60 bona fide {alpha}-enhanced stars and of 146 stars with solar-scaled abundances. The properties of the detected {alpha}-enhanced and solar-scaled abundance stars with respect to their [Fe/H] values and kinematics are presented. A clear kinematic distinction between solar-scaled and {alpha}-enhanced stars was found, although a one-to-one correspondence to "thin disk" and "thick disk" components cannot be supported with the present data.