We present and use new spectra and narrowband images, along with previously published broadband images, of stars in the Arches cluster to extract photometry, astrometry, equivalent width, and velocity information. The data are interpreted with a wind/atmosphere code to determine stellar temperatures, luminosities, mass-loss rates, and abundances. We have doubled the number of known emission-line stars, and we have also made the first spectroscopic identification of the main sequence for any population in the Galactic center.