We report the first results from an imaging program with the ACS on the Hubble Space Telescope designed to measure the structural characteristics of a wide range of globular clusters in NGC 5128, the nearest giant elliptical galaxy. From 12 ACS WFC fields we have measured a total of 62 previously known globular clusters and have discovered 69 new high-probability cluster candidates not found in any previous work. We present magnitudes and color indices for all of these, along with rough measurements of their effective diameters and ellipticities.