We present a new catalog of 108 Herbig Ae/Be candidate stars identified in the Pico dos Dias Survey (Gregorio-Hete et al., 1992AJ....103..549G; Torres et al., 1995AJ....109.2146T and 1999, Special Publ. 10, Rio de Janeiro: Obs. Nac.), together with 19 previously known candidates and four objects selected from the IRAS Faint Source Catalog (<II/156>). These 131 stars were observed with low- and/or medium-resolution spectroscopy, and we complement these data with high-resolution spectra of 39 stars.