From observations at the European Southern Observatory, spectrographic and photometric data are presented for 91 supergiant stars belonging to the Small Magellanic Cloud and its Wing. The data include MK classes for 52 stars, radial velocity data for 51 stars and UBV photometry for 90 stars. In V the limiting magnitude for the spectrographic observations is 13.7 and for the photometric observations 13.9. Whenever possible, radial velocities for interstellar CaII and [OII] have been measured and listed. In Remarks to the Catalogue notes are given for the individual stars concerning the obtained data and comparisons with results of previous investigations.