THz spectrum of methylamine Virtual Observatory Resource

Authors
  1. Motiyenko R.A.
  2. Ilyushin
  3. V.V.
  4. Drouin B.J.
  5. Yu.S.
  6. Margules L.
  7. Published by
    CDS
Abstract

Methylamine (CH_3_NH_2_) is the simplest primary alkylamine and has been detected in the interstellar medium. The molecule is relatively light, with the 50K Boltzmann peak appearing near 800GHz. However, reliable predictions for its rotational spectrum are available only up to 500GHz. Spectroscopic analyses have been complicated by the two large amplitude motions: internal rotation of the methyl top and inversion of the amino group. The aims is to provide reliable predictions of the methylamine ground state rotational spectrum above 500GHz we studied its rotational spectrum in the frequency range from 500 to 2650GHz. The spectra of methylamine were recorded using the spectrometers based on Schottky diode frequency multiplication chains in the Lille laboratory (500-945GHz) and in JPL (1060-2660GHz). The analysis of the rotational spectrum of methylamine in the ground vibrational state was performed on the basis of the group-theoretical high barrier tunneling Hamiltonian developed for methylamine by Ohashi and Hougen. In the recorded spectra we have assigned 1849 new rotational transitions of methylamine. They were fitted together with previously published data to a Hamiltonian model that uses 76 parameters with overall weighted rms deviation of 0.87. On the basis of the new spectroscopic results, predictions of transition frequencies in the frequency range up to 3THz with J<50 and Ka<20 are presented.

Keywords
  1. atomic-physics
  2. interstellar-medium
  3. millimeter-astronomy
  4. submillimeter-astronomy
Bibliographic source Bibcode
2014A&A...563A.137M
See also HTML
https://cdsarc.cds.unistra.fr/viz-bin/cat/J/A+A/563/A137
IVOA Identifier IVOID
ivo://CDS.VizieR/J/A+A/563/A137
Document Object Identifer DOI
doi:10.26093/cds/vizier.35630137

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History

2014-03-25T07:05:36Z
Resource record created
2014-03-25T07:05:36Z
Created
2014-09-03T12:40:32Z
Updated

Contact

Name
CDS support team
Postal Address
CDS, Observatoire de Strasbourg, 11 rue de l'Universite, F-67000 Strasbourg, France
E-Mail
cds-question@unistra.fr