Detailed chemical abundances of volatile and refractory elements have been discussed in the context of terrestrial-planet formation during in past years. The HARPS-GTO high-precision planet-search program has provided an extensive database of stellar spectra, which we have inspected in order to select the best-quality spectra available for late type stars. We study the volatile-to-refractory abundance ratios to investigate their possible relation with the low-mass planetary formation.