The physical properties of almost any kind of astronomical object can be derived by fitting synthetic spectra or photometry extracted from theoretical models to observational data. We want to develop an automatic procedure to perform this kind of fitting to a relatively large sample of members of a stellar association and apply this methodology to the case of Collinder 69. We combine the multiwavelength data of our sources and follow a work-flow to derive the physical parameters of the sources. The key step of the work-flow is performed by a new VO-tool, VOSA. All the steps in this process are done in a VO environment.