(De)excitation rates of H2O by H2 Virtual Observatory Resource

Authors
  1. Faure A.
  2. Crimier N.
  3. Ceccarelli C.
  4. Valiron P.
  5. Wiesenfeld L.
  6. Dubernet L.
  7. Published by
    CDS
Abstract

The interpretation of water line emission from existing observations and future HIFI/Herschel data requires a detailed knowledge of collisional rate coefficients. Among all relevant collisional mechanisms, the rotational (de)excitation of H2O by H2 molecules is the process of most interest in interstellar space. We provide rate coefficients for rotational de-excitation among the lowest 45 para and 45 ortho rotational levels of H2O colliding with both para and ortho-H2 in the temperature range 20-2000K. Rate coefficients are calculated on a recent high-accuracy H2O-H2 potential energy surface using quasi-classical trajectory calculations. Trajectories are sampled by a canonical Monte-Carlo procedure. H2 molecules are assumed rotationally thermalized at the kinetic temperature. By comparison with quantum calculations available for low lying levels, classical rates are found to be accurate within a factor of 1-3 for the dominant transitions, that is those with rates larger than a few 10^-12^cm^3^/s. Large velocity gradient modelling shows that the new rates have a significant impact on emission line fluxes and that they should be adopted in any detailed population model of water in warm and hot environments.

Keywords
  1. atomic-physics
Bibliographic source Bibcode
2007A&A...472.1029F
See also HTML
https://cdsarc.cds.unistra.fr/viz-bin/cat/J/A+A/472/1029
IVOA Identifier IVOID
ivo://CDS.VizieR/J/A+A/472/1029
Document Object Identifer DOI
doi:10.26093/cds/vizier.34721029

Access

Web browser access HTML
http://vizier.cds.unistra.fr/viz-bin/VizieR-2?-source=J/A+A/472/1029
https://vizier.iucaa.in/viz-bin/VizieR-2?-source=J/A+A/472/1029
http://vizieridia.saao.ac.za/viz-bin/VizieR-2?-source=J/A+A/472/1029
IVOA Table Access TAP
http://tapvizier.cds.unistra.fr/TAPVizieR/tap
Run SQL-like queries with TAP-enabled clients (e.g., TOPCAT).

History

2008-03-14T12:24:11Z
Resource record created
2008-03-14T12:24:11Z
Created
2017-12-05T05:10:31Z
Updated

Contact

Name
CDS support team
Postal Address
CDS, Observatoire de Strasbourg, 11 rue de l'Universite, F-67000 Strasbourg, France
E-Mail
cds-question@unistra.fr