High spectral resolution (FWHM = 0.6 or 0.35 {AA}) were obtained for six high redshift QSOs, z_em_ > 2.2, containing lines from 31 metal-rich absorption line systems amongst which 20 Civ doublets split in subcomponents with velocity differences within a system smaller than 400 km.s^-1^. Our survey has been combined with published data at similar resolution and the resulting sample comprises 35 systems, 23 of which are splitted in a total of 87 subcomponents. The mean redshift of the sample is <z> = 2.65. The observations were carried out at the F/8 Cassegrain focus of the 3.6m telescope at la Silla, between 1984 and 1989.