The catalogue of radial velocities of Galactic stars with high precision astrometric data (CRVAD) is the result of a merging of star lists from the General Catalog of Mean Radial Velocities (GCRV, Cat. III/213) and from the All-sky Compiled Catalogue of 2.5 Million Stars (ASCC-2.5, Cat. I/280). The cross identification of GCRV and ASCC-2.5 objects was carried out with help of coordinate, magnitude, colour and/or spectral type criteria. Data from the Catalogue of Components of Double and Multiple Stars (CCDM, Cat. I/274) were taken into account for the identification of multiple system components. 34553 stars of the ASCC-2.5 were identified with 33509 stars of the GCRV, i.e. 33509 stars of the GCRV have one entry in the ASCC-2.5, and 1044 objects have two entries. The catalogue includes accurate equatorial coordinates J2000, proper motions and trigonometric parallaxes in the Hipparcos system, B and V magnitudes in Johnson system, spectral classes, multiplicity and variability flags from the ASCC-2.5, and radial velocities, stellar magnitudes and spectra from the GCRV. Stars are sorted in right ascension J2000 order. 3967 stars were selected as radial velocity standard candidates (file rv_std.dat). These stars: - do not have any multiplicity and/or variability flags both in the GCRV and ASCC-2.5; - have standard errors of equatorial coordinates e <= 40 mas; - have standard errors of proper motions e_pm <= 4 mas/yr; - have standard errors of V magnitude e_V <= 0.05 mag and (B-V) colour e_(B-V) <= 0.07 mag; - have standard errors of radial velocity e_RV <= 2 km/s or quality index A or B, which corresponds to e_RV 0.74 and 1.78 km/s; - have at least four RV observations N_RV.