Photoelectric photometry of the K-line of calcium has been performed for the A stars of five open clusters (Hyades, Pleiades, IC 2391, IC 2602, and NGC 6475) and one association (Orion). All observations were carried out simultaneously with the field stars measurements in Paper II (II/43), with the 16-inch (40cm) and 36-inch (91cm) telescopes of the Cerro Tololo Inter-American Observatory, between May 1969 and January 1970.