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<ri:Resource created="2016-03-11T15:16:57Z" status="active" updated="2025-06-13T15:25:00Z" version="1.2" xmlns:ri="http://www.ivoa.net/xml/RegistryInterface/v1.0" xmlns:vr="http://www.ivoa.net/xml/VOResource/v1.0" xmlns:vs="http://www.ivoa.net/xml/VODataService/v1.1" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.ivoa.net/xml/VOResource/v1.0 http://vo.ari.uni-heidelberg.de/docs/schemata/VOResource.xsd http://www.ivoa.net/xml/VODataService/v1.1 http://vo.ari.uni-heidelberg.de/docs/schemata/VODataService.xsd" xsi:type="vs:CatalogService"><title>Empirical methane (CH_4_) line list</title><shortName>J/ApJ/813/12</shortName><identifier>ivo://CDS.VizieR/J/ApJ/813/12</identifier><altIdentifier>doi:10.26093/cds/vizier.18130012</altIdentifier><curation><publisher ivo-id="ivo://CDS">CDS</publisher><creator><name>Hargreaves R.J.</name></creator><creator><name>Bernath P.F.</name></creator><creator><name>Bailey J.</name></creator><creator><name>Dulick M.</name></creator><date role="Updated">2017-01-23T22:00:00Z</date><date role="Created">2016-03-11T15:16:57Z</date><contact><name>CDS support team</name><address>CDS, Observatoire de Strasbourg, 11 rue de l'Universite, F-67000 Strasbourg, France</address><email>cds-question@unistra.fr</email></contact></curation><content><subject>atomic-physics</subject><subject>spectroscopy</subject><subject>infrared-astronomy</subject><description>Hot methane is found in many "cool" sub-stellar astronomical sources including brown dwarfs and exoplanets, as well as in combustion environments on Earth. We report on the first high-resolution laboratory absorption spectra of hot methane at temperatures up to 1200K. Our observations are compared to the latest theoretical spectral predictions and recent brown dwarf spectra. The expectation that millions of weak absorption lines combine to form a continuum, not seen at room temperature, is confirmed. Our high-resolution transmittance spectra account for both the emission and absorption of methane at elevated temperatures. From these spectra, we obtain an empirical line list and continuum that is able to account for the absorption of methane in high temperature environments at both high and low resolution. Great advances have recently been made in the theoretical prediction of hot methane, and our experimental measurements highlight the progress made and the problems that still remain.</description><source format="bibcode">2015ApJ...813...12H</source><referenceURL>https://cdsarc.cds.unistra.fr/viz-bin/cat/J/ApJ/813/12</referenceURL><type>Catalog</type><contentLevel>Research</contentLevel><relationship><relationshipType>IsServedBy</relationshipType><relatedResource ivo-id="ivo://CDS.VizieR/TAP">TAP VizieR generic service</relatedResource></relationship><relationship><relationshipType>related-to</relationshipType><relatedResource ivo-id="ivo://CDS.VizieR/J/MNRAS/440/1649">J/MNRAS/440/1649 : ExoMol line lists for CH4 (Yurchenko+, 2014)</relatedResource><relatedResource ivo-id="ivo://CDS.VizieR/J/ApJ/757/46">J/ApJ/757/46 : Hot methane (CH4) line list (Hargreaves+, 2012)</relatedResource><relatedResource ivo-id="ivo://CDS.VizieR/J/ApJ/735/111">J/ApJ/735/111 : NH_3_ line lists at high temperatures (Hargreaves+, 2011)</relatedResource><relatedResource ivo-id="ivo://CDS.VizieR/J/ApJ/708/1452">J/ApJ/708/1452 : Quadratic F_ij_ force field in l-CH_4_^-^ (Senent+, 2010)</relatedResource><relatedResource ivo-id="ivo://CDS.VizieR/J/ApJ/637/1067">J/ApJ/637/1067 : NIR spectral classification of T dwarfs (Burgasser+, 2006)</relatedResource><relatedResource ivo-id="ivo://CDS.VizieR/J/other/ARA+A/43.195">J/other/ARA+A/43.195 : L and T dwarf stars (Kirkpatrick, 2005)</relatedResource></relationship></content><rights>https://cds.unistra.fr/vizier-org/licences_vizier.html</rights><capability><interface xsi:type="vr:WebBrowser"><accessURL use="full">https://vizier.cds.unistra.fr/viz-bin/VizieR-2?-source=J/ApJ/813/12</accessURL><mirrorURL title="VizieR at IUCAA: Pune, India">https://vizier.iucaa.in/viz-bin/VizieR-2?-source=J/ApJ/813/12</mirrorURL><mirrorURL title="VizieR at SAAO: SAAO, South Africa">http://vizieridia.saao.ac.za/viz-bin/VizieR-2?-source=J/ApJ/813/12</mirrorURL></interface></capability><capability><interface xsi:type="vs:ParamHTTP"><accessURL use="base">https://vizier.cds.unistra.fr/viz-bin/votable?-source=J/ApJ/813/12</accessURL><mirrorURL title="VizieR at IUCAA: Pune, India">https://vizier.iucaa.in/viz-bin/votable?-source=J/ApJ/813/12</mirrorURL><mirrorURL title="VizieR at SAAO: SAAO, South Africa">http://vizieridia.saao.ac.za/viz-bin/votable?-source=J/ApJ/813/12</mirrorURL><queryType>GET</queryType><resultType>text/xml+votable</resultType></interface></capability><capability standardID="ivo://ivoa.net/std/TAP#aux"><interface xsi:type="vs:ParamHTTP" role="std"><accessURL use="base">https://tapvizier.cds.unistra.fr/TAPVizieR/tap</accessURL></interface></capability><coverage><footprint ivo-id="ivo://ivoa.net/std/moc"/><waveband>Infrared</waveband></coverage><tableset><schema><name>default</name><table><name>J/ApJ/813/12/table3</name><description>CH_4_ line list</description><column><name>recno</name><description>Record number assigned by the VizieR team. Should Not be used for identification.</description><ucd>meta.record</ucd><dataType xsi:type="vs:VOTableType">int</dataType></column><column><name>T</name><description>[200/900] Temperature in {deg}C</description><unit>degC</unit><ucd>phys.temperature</ucd><dataType xsi:type="vs:VOTableType">int</dataType></column><column><name>nu</name><description>[2600/4884.1] Wavenumber (line position {bar}{nu})</description><unit>cm**-1</unit><ucd>em.freq</ucd><dataType xsi:type="vs:VOTableType">double</dataType></column><column><name>S'</name><description>Line intensity in units of cm/molecule</description><ucd>spect.line.intensity</ucd><dataType xsi:type="vs:VOTableType">double</dataType></column><column><name>E</name><description>[0/17440]? Lower state energy E" (1)</description><unit>cm**-1</unit><ucd>phys.energy;phys.atmol.level</ucd><dataType xsi:type="vs:VOTableType">double</dataType><flag>nullable</flag></column><column><name>QC</name><description>Quality code (1=E" is the most accurate) (2)</description><ucd>meta.code.qual</ucd><dataType xsi:type="vs:VOTableType" arraysize="1*">char</dataType></column></table></schema></tableset></ri:Resource>