J/A+A/615/A176ivo://CDS.VizieR/J/A+A/615/A176doi:10.26093/cds/vizier.36150176CDSDegli Esposti C.Dore L.Puzzarini C.Biczysko M.Bloino J.,Bizzocchi L.Lattanzi V.Grabow J.-U.2018-08-22T08:08:04Z2018-08-07T08:37:48ZCDS support team

CDS, Observatoire de Strasbourg, 11 rue de l'Universite, F-67000 Strasbourg, France

cds-question@unistra.frspectroscopyTo date, several complex organic molecules have been detected in the interstellar medium, and they have been suggested as precursors of biologically important species. Propargylamine (HC{triple}C-CH_2_-NH_2_) is structurally similar to a number of other organic molecules which have already been identified by radioastronomy, making it a good candidate for astrophysical detection. This work provides accurate rest frequencies of propargylamine, from the centimeter-wave to the submillimeter-wave region, useful to facilitate the detection of this molecule in the interstellar medium. An extensive laboratory study of the rotational spectrum of propargylamine has been performed using a pulsed-jet Fourier Transform Microwave (FTMW) spectrometer (7-19GHz frequency range) and a frequency modulation microwave spectrometer (75-560GHz). Several hundred rotational transitions of propargylamine were recorded in the ground and three lowest excited vibrational states. The experiments were supported by high-level ab initio computations, mainly employed to characterize the vibrational state structure and to predict spectroscopic parameters unknown prior to this study. The measured transition frequencies yielded accurate rotational constants and the complete sets of quartic and sextic centrifugal distortion constants for propargylamine in its vibrational ground state. ^14^N-nuclear quadrupole coupling constants were also determined. Rotational and quartic centrifugal distortion constants were also obtained for the low-lying excited states v_13_=1(A'), v_20_=1(A"), and v_21_=1(A"). The a-type Coriolis resonance which couples the v_13_=1 and v_21_=1 levels was analyzed. The determined spectroscopic constants allowed for the compilation of a dataset of highly accurate rest frequencies for astrophysical purposes in the millimeter and submillimeter regions with 1{sigma} uncertainties that are smaller than 0.050MHz, corresponding to 0.03km/s at 500GHz in radial equivalent velocity.2018A&A...615A.176Dhttps://cdsarc.cds.unistra.fr/viz-bin/cat/J/A+A/615/A176CatalogResearchIsServedByTAP VizieR generic servicerelated-toJ/A+A/455/1161 : Rest frequencies of sub-mm spectrum of SiN (Bizzocchi+, 2006)J/A+A/492/875 : Rest frequencies for C_3_O (Bizzocchi+, 2008)J/A+A/544/A19 : CH_2_NH accurate rotational rest frequencies (Dore+, 2012)J/A+A/549/A38 : Millimetre and infrared spectrum of DC_4_H (Tamassia+, 2013)J/A+A/565/A66 : Ketenimine (CH_2_CNH) submm rest-frequenciesJ/ApJ/820/L26 : J=1-0 transitions of argonium (ArH^+^) (Bizzocchi+, 2016)J/ApJS/230/26 : NH_2_CH_2_CN transition frequencies (Degli Esposti+, 2017)J/ApJS/233/11 : Cyanoacetylene (HC_3_N) infrared spectrum (Bizzocchi+, 2017)J/ApJS/233/15 : ND_2_ rotational spectrum (Melosso+, 2017)J/A+A/609/A121 : Lab measurements for C-cyanomethanimine (Melosso+, 2018)https://cds.unistra.fr/vizier-org/licences_vizier.htmlhttps://vizier.cds.unistra.fr/viz-bin/VizieR-2?-source=J/A+A/615/A176https://vizier.iucaa.in/viz-bin/VizieR-2?-source=J/A+A/615/A176http://vizieridia.saao.ac.za/viz-bin/VizieR-2?-source=J/A+A/615/A176https://vizier.cds.unistra.fr/viz-bin/votable?-source=J/A+A/615/A176https://vizier.iucaa.in/viz-bin/votable?-source=J/A+A/615/A176http://vizieridia.saao.ac.za/viz-bin/votable?-source=J/A+A/615/A176GETtext/xml+votablehttps://tapvizier.cds.unistra.fr/TAPVizieR/tapdefaultJ/A+A/615/A176/table4Assignments, measured line positions, and least-squares residuals for the analysed transitions of propargylaminerecnoRecord number assigned by the VizieR team. Should Not be used for identification.meta.recordintJ1Upper state rotational quantum numberphys.atmol.qnintKa1Upper state rotational quantum numberphys.atmol.qnintKc1Upper state rotational quantum numberphys.atmol.qnintnu1Upper state vibrational label (1)phys.mol.qnintF1? Upper state total quantum number (2)phys.atmol.qnintnullableJ0Lower state rotational quantum numberphys.atmol.qnintKa0Lower state rotational quantum numberphys.atmol.qnintKc0Lower state rotational quantum numberphys.atmol.qnintnu0Lower state vibrational label (1)phys.mol.qnintF0? Lower state total quantum number (2)phys.atmol.qnintnullableObsMeasured line frequencyMHzem.freq;spect.linedoubleObs-calcLeast-squares residualMHzstat.fit.residualfloatUncertAssumed uncertaintyMHzstat.errorfloatWeight? Relative weight for blended transitionsstat.weight;phys.atmol.weightfloatnullable