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We undertook a spectroscopic survey of central stars of PNe at low resolution and compiled a large list of central stars for which information was dispersed in the literature. We present a catalogue of 492 confirmed and probable CSPN and provide a preliminary spectral classification for 45 central star of PNe. This revises previous values of the proportion of CSPN with atmospheres poor in hydrogen in at least 30% of cases and provide statistical information that allows us to infer the origin of H-poor stars. Based on data collected at the Complejo Astronomico El Leoncito (CASLEO), which is operated under agreement between the Consejo Nacional de Investigaciones Cientificas y Tecnicas de la Republica Argentina y Universidades Nacionales de La Plata, Cordoba y San Juan, Argentina.</description><source format="bibcode">2011A&amp;A...526A...6W</source><referenceURL>https://cdsarc.cds.unistra.fr/viz-bin/cat/J/A+A/526/A6</referenceURL><type>Catalog</type><contentLevel>Research</contentLevel><relationship><relationshipType>IsServedBy</relationshipType><relatedResource ivo-id="ivo://CDS.VizieR/TAP">TAP VizieR generic service</relatedResource></relationship><relationship><relationshipType>IsServedBy</relationshipType><relatedResource>Conesearch service</relatedResource></relationship><relationship><relationshipType>related-to</relationshipType><relatedResource ivo-id="ivo://CDS.VizieR/V/84">V/84 : Strasbourg-ESO Catalogue of Galactic Planetary Nebulae (Acker+, 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