J/MNRAS/490/1652ivo://CDS.VizieR/J/MNRAS/490/1652doi:10.26093/cds/vizier.74901652CDSGroman M.N.Yurchenko S.N.Tennyson J.2024-08-20T20:13:34Z2020-01-22T08:55:42ZCDS support team

CDS, Observatoire de Strasbourg, 11 rue de l'Universite, F-67000 Strasbourg, France

cds-question@unistra.fratomic-physicsThe GYT line list covering rotational, rovibrational and rovibronic transitions of the mercapto radical SH is presented. This work extends and replaces the SNaSH line list (Yurchenko et al., 2018, Cat. J/MNRAS/478/270) which covers the ground (electronic) X ^2^{Pi} state only. This extension is prompted by the tentative identification of the ultra-violet features of SH as being of importance in the transmission spectrum of the ultra-hot Jupiter exoplanet WASP-121b (Evans et al., 2018AJ....156..283E). This GYT line list model is generated by fitting empirical potential energy, spin-orbit and electronic angular momenta functions to experimentally measured wavelengths within the X ^2^{Pi} and A ^2^{Simga}^+^ states and to the A ^2^{Sigma}^+^ - X ^2^{Pi} band system using ab initio curves as a starting reference point. The fits are compatible with the quoted uncertainty of the experimental data used of ~0.03-0.3cm^-1^. The GYT line list covers wavelengths longer than 0.256um and includes 7686 rovibronic states and 572145 transitions for ^32^SH. Line lists for the ^33^SH, ^34^SH, ^36^SH and ^32^SD isotopologues are generated including a consideration of non-Born-Oppenheimer effects for SD. The line lists are available from the CDS (http://cdsarc.u-strasbg.fr) and ExoMol (www.exomol.com) data bases.2019MNRAS.490.1652Ghttps://cdsarc.cds.unistra.fr/viz-bin/cat/J/MNRAS/490/1652CatalogResearchIsServedByTAP VizieR generic servicerelated-toJ/MNRAS/425/34 : ExoMol line lists for BeH, MgH and CaH (Yadin+, 2012)J/MNRAS/434/1469 : ExoMol line lists for SiO (Barton+, 2013)J/MNRAS/437/1828 : ExoMol line lists for HCN and HNC (Barber+, 2014)J/MNRAS/440/1649 : ExoMol line lists for CH4 (Yurchenko+, 2014)J/MNRAS/442/1821 : ExoMol line lists for KCl (Barton+, 2014)J/MNRAS/445/1383 : ExoMol line lists for phosphorus nitride (PN) (Yorke+, 2014)J/MNRAS/446/2337 : ExoMol line lists for phosphine (PH_3_) (Sousa-Silva+, 2015)J/MNRAS/448/1704 : ExoMol line lists for formaldehyde H_2_CO (Al-Refaie+, 2015)J/MNRAS/449/3613 : ExoMol line lists for AlO (Patrascu+, 2015)J/MNRAS/451/634 : ExoMol line lists for NaH and NaD (Rivlin+, 2015)J/MNRAS/452/1702 : ExoMol line lists for HNO3 (Pavlyuchko+, 2015)J/MNRAS/454/1931 : ExoMol line lists for CS isotopologues (Paulose+, 2015)J/MNRAS/456/4524 : ExoMol line lists for CaO (Yurchenko+, 2016)J/MNRAS/459/3890 : ExoMol line lists for SO2 (Underwood+, 2016)J/MNRAS/461/1012 : ExoMol line lists for H216O2 (Al-Refaie+, 2016)J/MNRAS/462/4300 : ExoMol line lists. XVII: SO3 (Underwood+, 2016)J/MNRAS/463/771 : ExoMol. VO high-temperature spectrum (McKemmish+, 2016)J/MNRAS/466/1363 : ExoMol line lists for H_2_^18^O & H_2_^17^OJ/MNRAS/468/1717 : ExoMol molecular line lists for H3+ (Mizus+, 2017)J/MNRAS/470/882 : ExoMol line lists. XXI: Nitric Oxide (NO) (Wong+, 2017)J/MNRAS/471/5025 : ExoMol line lists for ^28^SiH_4_ (Owens+, 2017)J/MNRAS/473/5324 : ExoMol line lists. XXIV. SiH (Yurchenko+, 2018)J/MNRAS/479/3002 : ExoMol line lists. XXIX. CH3Cl (Owens+, 2018)J/MNRAS/480/3397 : ExoMol line lists. XXXI: C_2_ (Yurchenko+, 2018)J/MNRAS/486/2351 : ExoMol line lists. XXXII. MgO (Li+, 2019)J/MNRAS/488/2332 : ExoMol line lists. XXXIV. PH (Langleben+, 2019)J/MNRAS/488/2836 : ExoMol line lists. XXXIII. TiO (McKemmish+, 2019)https://cds.unistra.fr/vizier-org/licences_vizier.htmlhttps://vizier.cds.unistra.fr/viz-bin/VizieR-2?-source=J/MNRAS/490/1652https://vizier.iucaa.in/viz-bin/VizieR-2?-source=J/MNRAS/490/1652http://vizieridia.saao.ac.za/viz-bin/VizieR-2?-source=J/MNRAS/490/1652https://vizier.cds.unistra.fr/viz-bin/votable?-source=J/MNRAS/490/1652https://vizier.iucaa.in/viz-bin/votable?-source=J/MNRAS/490/1652http://vizieridia.saao.ac.za/viz-bin/votable?-source=J/MNRAS/490/1652GETtext/xml+votablehttps://tapvizier.cds.unistra.fr/TAPVizieR/tapdefaultJ/MNRAS/490/1652/pf-32s1hPartition function for the ^32^S^1^H isotopologueQParition functionphys.atmoldoubleTTemperature in KelvinKphys.temperaturedoublerecnoRecord number assigned by the VizieR team. Should Not be used for identification.meta.recordintJ/MNRAS/490/1652/pf-32s2hPartition function for the ^32^S^2^H isotopologuerecnoRecord number assigned by the VizieR team. Should Not be used for identification.meta.recordintTTemperature in KelvinKphys.temperaturedoubleQParition functionphys.atmoldoubleJ/MNRAS/490/1652/pf-33s1hPartition function for the ^33^S^1^H isotopologuerecnoRecord number assigned by the VizieR team. Should Not be used for identification.meta.recordintTTemperature in KelvinKphys.temperaturedoubleQParition functionphys.atmoldoubleJ/MNRAS/490/1652/pf-34s1hPartition function for the ^34^S^1^H isotopologuerecnoRecord number assigned by the VizieR team. Should Not be used for identification.meta.recordintTTemperature in KelvinKphys.temperaturedoubleQParition functionphys.atmoldoubleJ/MNRAS/490/1652/pf-36s1hPartition function for the ^35^S^1^H isotopologuerecnoRecord number assigned by the VizieR team. Should Not be used for identification.meta.recordintTTemperature in KelvinKphys.temperaturedoubleQParition functionphys.atmoldouble