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<ri:Resource created="2025-10-31T09:27:18Z" status="active" updated="2026-07-02T12:00:20Z" version="1.2" xmlns:cs="http://www.ivoa.net/xml/ConeSearch/v1.0" xmlns:ri="http://www.ivoa.net/xml/RegistryInterface/v1.0" xmlns:vr="http://www.ivoa.net/xml/VOResource/v1.0" xmlns:vs="http://www.ivoa.net/xml/VODataService/v1.1" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.ivoa.net/xml/ConeSearch/v1.0 http://vo.ari.uni-heidelberg.de/docs/schemata/ConeSearch.xsd http://www.ivoa.net/xml/VOResource/v1.0 http://vo.ari.uni-heidelberg.de/docs/schemata/VOResource.xsd http://www.ivoa.net/xml/VODataService/v1.1 http://vo.ari.uni-heidelberg.de/docs/schemata/VODataService.xsd" xsi:type="vs:CatalogService"><title>Abundances in warm VMP stars from Keck/HIRES sp.</title><shortName>J/ApJ/953/31</shortName><identifier>ivo://CDS.VizieR/J/ApJ/953/31</identifier><altIdentifier>doi:10.26093/cds/vizier/ba-xs-z</altIdentifier><curation><publisher ivo-id="ivo://CDS">CDS</publisher><creator><name>Sneden C.</name></creator><creator><name>Boesgaard A.M.</name></creator><creator><name>Cowan J.J.</name></creator><creator><name>Roederer I.U.</name></creator><creator><name>Den Hartog E.A.,Lawler J.E.</name></creator><date role="Updated">2026-07-02T12:00:20Z</date><date role="Created">2025-10-31T09:27:18Z</date><contact><name>CDS support team</name><address>CDS, Observatoire de Strasbourg, 11 rue de l'Universite, F-67000 Strasbourg, France</address><email>cds-question@unistra.fr</email></contact></curation><content><subject>chemical-abundances</subject><subject>chemically-peculiar-stars</subject><subject>visible-astronomy</subject><subject>spectroscopy</subject><subject>ultraviolet-astronomy</subject><description>We have derived new detailed abundances of Mg, Ca, and the Fe-group elements Sc through Zn (Z=21-30) for 37 main-sequence turnoff very metal-poor stars ([Fe/H]&lt;~-2.1). We analyzed Keck HIRES optical and near-UV high signal-to-noise spectra originally gathered for a Be abundance survey. Using typically ~400 Fe-group lines with accurate laboratory transition probabilities for each star, we have determined accurate LTE metallicities and abundance ratios for neutral and ionized species of the 10 Fe-group elements as well as {alpha} elements Mg and Ca. We find good neutral/ion abundance agreement for the six elements that have detectable transitions of both species in our stars in the 3100-5800{AA} range. Earlier reports of correlated Sc-Ti-V relative overabundances are confirmed, and appear to slowly increase with decreasing metallicity. To this element trio we add Zn; it also appears to be increasingly overabundant in the lowest-metallicity regimes. Co appears to mimic the behavior of Zn, but issues surrounding its abundance reliability cloud its interpretation.</description><source format="bibcode">2023ApJ...953...31S</source><referenceURL>https://cdsarc.cds.unistra.fr/viz-bin/cat/J/ApJ/953/31</referenceURL><type>Catalog</type><contentLevel>Research</contentLevel><relationship><relationshipType>IsServedBy</relationshipType><relatedResource ivo-id="ivo://CDS.VizieR/TAP">TAP VizieR generic service</relatedResource></relationship><relationship><relationshipType>IsServedBy</relationshipType><relatedResource>Conesearch service</relatedResource></relationship><relationship><relationshipType>related-to</relationshipType><relatedResource ivo-id="ivo://CDS.VizieR/I/337">I/337 : Gaia DR1 (Gaia Collaboration, 2016)</relatedResource><relatedResource ivo-id="ivo://CDS.VizieR/I/357">I/357 : Gaia DR3 Part 3. 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Should Not be used for identification.</description><ucd>meta.record</ucd><dataType xsi:type="vs:VOTableType">int</dataType></column><column><name>Name</name><description>Star name</description><ucd>meta.id;meta.main</ucd><dataType xsi:type="vs:VOTableType" arraysize="11*">char</dataType><flag>primary</flag></column><column><name>Teff</name><description>[5500/6350] Effective temperature</description><unit>K</unit><ucd>phys.temperature.effective</ucd><dataType xsi:type="vs:VOTableType">int</dataType></column><column><name>logg</name><description>[3.1/4.5] Log of surface gravity</description><unit>log(cm.s**-2)</unit><ucd>phys.gravity</ucd><dataType xsi:type="vs:VOTableType">float</dataType></column><column><name>Vt</name><description>[1/1.5] Microturbulent velocity, {xi}_t_</description><unit>km/s</unit><ucd>phys.veloc.microTurb</ucd><dataType xsi:type="vs:VOTableType">float</dataType></column><column><name>[FeI/H]</name><description>[-3.6/-1.4] [Fe/H], FeI transition</description><unit>Sun</unit><ucd>phys.abund.Fe;phys.atmol.transition</ucd><dataType xsi:type="vs:VOTableType">float</dataType></column><column><name>e_[FeI/H]</name><description>[0.08/0.12] [FeI/H] uncertainty</description><unit>Sun</unit><ucd>stat.error;phys.abund.Fe</ucd><dataType xsi:type="vs:VOTableType">float</dataType></column><column><name>NlFeI</name><description>[85/288] Number of FeI lines used</description><ucd>meta.number</ucd><dataType xsi:type="vs:VOTableType">int</dataType></column><column><name>[FeII/H]</name><description>[-3.51/-1.44] [Fe/H], FeII transition</description><unit>Sun</unit><ucd>phys.abund.Fe;phys.atmol.transition</ucd><dataType xsi:type="vs:VOTableType">float</dataType></column><column><name>e_[FeII/H]</name><description>[0.08/0.16] [FeII/H] uncertainty</description><unit>Sun</unit><ucd>stat.error;phys.abund.Fe</ucd><dataType xsi:type="vs:VOTableType">float</dataType></column><column><name>NlFeII</name><description>[7/25] Number of FeII lines used</description><ucd>meta.number</ucd><dataType xsi:type="vs:VOTableType">int</dataType></column><column><name>B11</name><description>Display data from Boesgaard+ 2011, J/ApJ/743/140</description><ucd>meta.ref.url</ucd><dataType xsi:type="vs:VOTableType" arraysize="*">char</dataType></column><column><name>Abund</name><description>Display the abundances for this star (link to Table 2)</description><ucd>meta.ref.url</ucd><dataType xsi:type="vs:VOTableType" arraysize="*">char</dataType></column><column><name>SimbadName</name><description>Simbad column added by the CDS</description><ucd>meta.id</ucd><dataType xsi:type="vs:VOTableType" arraysize="11*">char</dataType><flag>nullable</flag></column><column><name>_RA</name><description>Right Ascension (J2000) from SIMBAD (not part of the original data)</description><unit>deg</unit><ucd>pos.eq.ra;meta.main</ucd></column><column><name>_DE</name><description>Declination (J2000) from SIMBAD (not part of the original data)</description><unit>deg</unit><ucd>pos.eq.dec;meta.main</ucd></column></table><table><name>J/ApJ/953/31/table2</name><description>Abundances for individual stars</description><column><name>recno</name><description>Record number assigned by the VizieR team. Should Not be used for identification.</description><ucd>meta.record</ucd><dataType xsi:type="vs:VOTableType">int</dataType></column><column><name>Name</name><description>Star name</description><ucd>meta.id;meta.main</ucd><dataType xsi:type="vs:VOTableType" arraysize="11*">char</dataType></column><column><name>[Fe/H]</name><description>[-3.56/-1.42] Metallicity (1)</description><unit>log(Sun)</unit><ucd>phys.abund.Z</ucd><dataType xsi:type="vs:VOTableType">float</dataType></column><column><name>Species</name><description>Species identifier (2)</description><ucd>phys.atmol.ionStage</ucd><dataType xsi:type="vs:VOTableType" arraysize="11*">char</dataType></column><column><name>[X/Fe]</name><description>[-0.92/0.7]? Abundance ratio of Species relative to iron</description><unit>log(Sun)</unit><ucd>phys.abund</ucd><dataType xsi:type="vs:VOTableType">float</dataType><flag>nullable</flag></column><column><name>e_[X/Fe]</name><description>[0/0.3]? 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