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<ri:Resource created="2023-10-09T10:42:09Z" status="active" updated="2025-05-22T20:11:52Z" version="1.2" xmlns:cs="http://www.ivoa.net/xml/ConeSearch/v1.0" xmlns:ri="http://www.ivoa.net/xml/RegistryInterface/v1.0" xmlns:vr="http://www.ivoa.net/xml/VOResource/v1.0" xmlns:vs="http://www.ivoa.net/xml/VODataService/v1.1" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.ivoa.net/xml/ConeSearch/v1.0 http://vo.ari.uni-heidelberg.de/docs/schemata/ConeSearch.xsd http://www.ivoa.net/xml/VOResource/v1.0 http://vo.ari.uni-heidelberg.de/docs/schemata/VOResource.xsd http://www.ivoa.net/xml/VODataService/v1.1 http://vo.ari.uni-heidelberg.de/docs/schemata/VODataService.xsd" xsi:type="vs:CatalogService"><title>Nature of PAH in PG quasars from Spitzer/IRS sp.</title><shortName>J/ApJ/925/218</shortName><identifier>ivo://CDS.VizieR/J/ApJ/925/218</identifier><altIdentifier>doi:10.26093/cds/vizier.19250218</altIdentifier><curation><publisher ivo-id="ivo://CDS">CDS</publisher><creator><name>Xie Y.</name></creator><creator><name>Ho L.C.</name></creator><date role="Updated">2025-05-22T20:11:52Z</date><date role="Created">2023-10-09T10:42:09Z</date><contact><name>CDS support team</name><address>CDS, Observatoire de Strasbourg, 11 rue de l'Universite, F-67000 Strasbourg, France</address><email>cds-question@unistra.fr</email></contact></curation><content><subject>quasars</subject><subject>infrared-astronomy</subject><subject>spectroscopy</subject><subject>redshifted</subject><subject>interstellar-medium</subject><subject>active-galactic-nuclei</subject><description>We reanalyze the mid-infrared (5-40{mu}m) Spitzer spectra of 86 low-redshift (z&lt;0.5) Palomar-Green quasars to investigate the nature of polycyclic aromatic hydrocarbon (PAH) emission and its utility as a star formation rate (SFR) indicator for the host galaxies of luminous active galactic nuclei (AGNs). We decompose the spectra with our recently developed template-fitting technique to measure PAH fluxes and upper limits, which we interpret using mock spectra that simulate the effects of AGN dilution. While luminous quasars can severely dilute and affect the detectability of emission lines, PAHs are intrinsically weak in some sources that are otherwise gas-rich and vigorously forming stars, conclusively demonstrating that powerful AGNs destroy PAH molecules. Comparing PAH-based SFRs with independent SFRs derived from the mid-infrared fine-structure neon lines and the total infrared luminosity reveals that PAHs can trace star formation activity in quasars with bolometric luminosities &lt;=10^46^erg/s, but increasingly underestimate the SFR for more powerful quasars, typically by ~0.5dex. Relative to star-forming galaxies and low-luminosity AGNs, quasars have a comparable PAH 11.3{mu}m/7.7{mu}m ratio but characteristically lower ratios of 6.2{mu}m/7.7{mu}m, 8.6{mu}m/7.7{mu}m, and 11.3{mu}m/17.0{mu}m. We suggest that these trends indicate that powerful AGNs preferentially destroy small grains and enhance the PAH ionization fraction.</description><source format="bibcode">2022ApJ...925..218X</source><referenceURL>https://cdsarc.cds.unistra.fr/viz-bin/cat/J/ApJ/925/218</referenceURL><type>Catalog</type><contentLevel>Research</contentLevel><relationship><relationshipType>IsServedBy</relationshipType><relatedResource ivo-id="ivo://CDS.VizieR/TAP">TAP VizieR generic service</relatedResource></relationship><relationship><relationshipType>IsServedBy</relationshipType><relatedResource>Conesearch service</relatedResource></relationship><relationship><relationshipType>related-to</relationshipType><relatedResource ivo-id="ivo://CDS.VizieR/VII/157">VII/157 : The Extended 12um galaxy sample (Rush+ 1993)</relatedResource><relatedResource ivo-id="ivo://CDS.VizieR/J/ApJ/269/352">J/ApJ/269/352 : Quasar evolution (Schmidt+, 1983)</relatedResource><relatedResource ivo-id="ivo://CDS.VizieR/J/A+A/357/839">J/A+A/357/839 : AGN 2.5-11um spectroscopy (Clavel+, 2000)</relatedResource><relatedResource ivo-id="ivo://CDS.VizieR/J/ApJ/653/127">J/ApJ/653/127 : 9.7um silicate features in AGNs (Shi+, 2006)</relatedResource><relatedResource ivo-id="ivo://CDS.VizieR/J/ApJ/656/770">J/ApJ/656/770 : Mid-IR spectrum of star-forming galaxies (Smith+, 2007)</relatedResource><relatedResource ivo-id="ivo://CDS.VizieR/J/ApJ/705/885">J/ApJ/705/885 : PAH in galaxies at z~0.1 (O'Dowd+, 2009)</relatedResource><relatedResource ivo-id="ivo://CDS.VizieR/J/ApJ/719/1191">J/ApJ/719/1191 : Mid-IR indicators of SF and AGN in galaxies (Treyer+, 2010)</relatedResource><relatedResource ivo-id="ivo://CDS.VizieR/J/ApJ/723/895">J/ApJ/723/895 : IR luminosities and aromatic features of 5MUSES (Wu+, 2010)</relatedResource><relatedResource ivo-id="ivo://CDS.VizieR/J/ApJ/758/1">J/ApJ/758/1 : SDSS-Spitzer AGN properties (LaMassa+, 2012)</relatedResource><relatedResource ivo-id="ivo://CDS.VizieR/J/ApJS/214/23">J/ApJS/214/23 : IR spectra and photometry of z&lt;0.5 quasars (Shi+, 2014)</relatedResource><relatedResource ivo-id="ivo://CDS.VizieR/J/ApJ/790/124">J/ApJ/790/124 : Dust and gas physics of the GOALS sample (Stierwalt+, 2014)</relatedResource><relatedResource ivo-id="ivo://CDS.VizieR/J/A+A/578/A74">J/A+A/578/A74 : Nuclear obscuration in LINERs (Gonzalez-Martin+, 2015)</relatedResource><relatedResource ivo-id="ivo://CDS.VizieR/J/ApJS/219/18">J/ApJS/219/18 : LIRAS: LoCuSS IR AGN survey (Xu+, 2015)</relatedResource><relatedResource ivo-id="ivo://CDS.VizieR/J/ApJ/819/L27">J/ApJ/819/L27 : Stellar masses of optical &amp; 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Upper uncertainty on logLPAH6</description><unit>log(1e-07W)</unit><ucd>stat.error;stat.max</ucd><dataType xsi:type="vs:VOTableType">float</dataType><flag>nullable</flag></column><column><name>l_logLPAH7</name><description>Limit flag on logLPAH7</description><ucd>meta.code.error</ucd><dataType xsi:type="vs:VOTableType" arraysize="1*">char</dataType></column><column><name>logLPAH7</name><description>[41.38/44] PAH luminosity at 7.7 um</description><unit>log(1e-07W)</unit><ucd>phys.luminosity;em.IR.4-8um</ucd><dataType xsi:type="vs:VOTableType">float</dataType></column><column><name>e_logLPAH7</name><description>[0.01/0.14]? Lower uncertainty on logLPAH7</description><unit>log(1e-07W)</unit><ucd>stat.error</ucd><dataType xsi:type="vs:VOTableType">float</dataType><flag>nullable</flag></column><column><name>E_logLPAH7</name><description>[0.01/0.14]? 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