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<ri:Resource created="2016-05-27T13:45:42Z" status="active" updated="2025-05-19T09:50:00Z" version="1.2" xmlns:ri="http://www.ivoa.net/xml/RegistryInterface/v1.0" xmlns:vr="http://www.ivoa.net/xml/VOResource/v1.0" xmlns:vs="http://www.ivoa.net/xml/VODataService/v1.1" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.ivoa.net/xml/VOResource/v1.0 http://vo.ari.uni-heidelberg.de/docs/schemata/VOResource.xsd http://www.ivoa.net/xml/VODataService/v1.1 http://vo.ari.uni-heidelberg.de/docs/schemata/VODataService.xsd" xsi:type="vs:CatalogService"><title>H_2_ d^3^{Pi}_u_ excitation by electron impact</title><shortName>J/ApJ/818/120</shortName><identifier>ivo://CDS.VizieR/J/ApJ/818/120</identifier><altIdentifier>doi:10.26093/cds/vizier.18180120</altIdentifier><curation><publisher ivo-id="ivo://CDS">CDS</publisher><creator><name>Liu X.</name></creator><creator><name>Shemansky D.E.</name></creator><creator><name>Yoshii J.</name></creator><creator><name>Johnson P.V.</name></creator><creator><name>Malone C.P.</name></creator><creator><name>Ajello J.M.</name></creator><date role="Updated">2017-01-23T22:00:00Z</date><date role="Created">2016-05-27T13:45:42Z</date><contact><name>CDS support team</name><address>CDS, Observatoire de Strasbourg, 11 rue de l'Universite, F-67000 Strasbourg, France</address><email>cds-question@unistra.fr</email></contact></curation><content><subject>atomic-physics</subject><description>Electron-impact excitation of H_2_ triplet states plays an important role in the heating of outer planet upper thermospheres. The d^3^{Pi}_u_ state is the third ungerade triplet state, and the d^3^{Pi}_u_-a^3^{Sigma}_g_^+^ emission is the largest cascade channel for the a^3^{Sigma}_g_^+^ state. Accurate energies of the d^3^{Pi}_u_^-^(v, J) levels are calculated from an ab initio potential energy curve. Radiative lifetimes of the d^3^{Pi}_u_(v,J) levels are obtained by an accurate evaluation of the d^3^{Pi}_u_-a^3^{Sigma}_g_^+^ transition probabilities. The emission yields are determined from experimental lifetimes and calculated radiative lifetimes and are further verified by comparing experimental and synthetic d^3^{Pi}_u_-a^3^{Sigma}_g_^+^ spectra at 20eV impact energy. Spectral analysis revealed that multipolar components beyond the dipolar term are required to model the X^1^{Sigma}_g_^+^-d^3^{Pi}_u_ excitation, and significant cascade excitation occurs at the d^3^{Pi}_u_ (v=0,1) levels. Kinetic energy (E_k_) distributions of H atoms produced via predissociation of the ^3^{Pi}_u_ state and the d^3^{Pi}_u_-a^3^{Sigma}_g_^+^-b^3^{Sigma}_u_^+^ cascade dissociative emission are obtained. Predissociation of the d^3^{Pi}_u_ state produces H atoms with an average E_k_ of 2.3+/-0.4 eV/atom, while the E_k_distribution of the d^3^{Pi}_u_-a^3^{Sigma}_g_^+^-b^3^{Sigma}_u_^+^ channel is similar to that of the X^1^{Sigma}_g_^+^-a^3^{Sigma}_g_^+^-b^3^{Sigma}_u_^+^ channel and produces H(1s) atoms with an average E_k_ of 1.15+/-0.05eV/atom. On average, each H_2_ excited to the d^3^{Pi}_u_ state in an H_2_-dominated atmosphere deposits 3.3+/-0.4eV into the atmosphere, while each H_2_directly excited to the a^3^{Sigma}_g_^+^ state gives 2.2-2.3eV to the atmosphere. The spectral distribution of the calculated a^3^{Sigma}_g_^+^-b^3^{Sigma}_u_^+^ continuum emission due to the X^1^{Sigma}_g_^+^-d^3^{Pi}_u_ excitation is significantly different from that of direct a^3^{Sigma}_g_^+^ excitation.</description><source format="bibcode">2016ApJ...818..120L</source><referenceURL>https://cdsarc.cds.unistra.fr/viz-bin/cat/J/ApJ/818/120</referenceURL><type>Catalog</type><contentLevel>Research</contentLevel><relationship><relationshipType>IsServedBy</relationshipType><relatedResource ivo-id="ivo://CDS.VizieR/TAP">TAP VizieR generic service</relatedResource></relationship><relationship><relationshipType>related-to</relationshipType><relatedResource ivo-id="ivo://CDS.VizieR/J/A+A/550/A12">J/A+A/550/A12 : NGC253 near-infrared H_2_ emission (Rosenberg+, 2013)</relatedResource><relatedResource ivo-id="ivo://CDS.VizieR/J/MNRAS/418/1994">J/MNRAS/418/1994 : GM 2-4 H_2_ emission-line objects (Khanzadyan+, 2011)</relatedResource><relatedResource ivo-id="ivo://CDS.VizieR/J/ApJ/711/1236">J/ApJ/711/1236 : Equivalent width of H_2_ from FUSE (Jensen+, 2010)</relatedResource><relatedResource ivo-id="ivo://CDS.VizieR/J/A+A/474/941">J/A+A/474/941 : Spectroscopy of H_2_ towards HH91A (Gredel+, 2007)</relatedResource><relatedResource ivo-id="ivo://CDS.VizieR/J/ApJS/165/256">J/ApJS/165/256 : Fluorescent H_2_ emission from T Tauri stars (Herczeg+, 2006)</relatedResource><relatedResource ivo-id="ivo://CDS.VizieR/J/A+AS/141/297">J/A+AS/141/297 : H_2_ total transition probability (Abgrall+, 2000)</relatedResource><relatedResource>http://www.nist.gov/pml/data/hdel : NIST energy levels of Hydrogen &amp; Deuterium</relatedResource></relationship></content><rights>https://cds.unistra.fr/vizier-org/licences_vizier.html</rights><capability><interface xsi:type="vr:WebBrowser"><accessURL use="full">https://vizier.cds.unistra.fr/viz-bin/VizieR-2?-source=J/ApJ/818/120</accessURL><mirrorURL title="VizieR at IUCAA: Pune, India">https://vizier.iucaa.in/viz-bin/VizieR-2?-source=J/ApJ/818/120</mirrorURL><mirrorURL title="VizieR at SAAO: SAAO, South Africa">http://vizieridia.saao.ac.za/viz-bin/VizieR-2?-source=J/ApJ/818/120</mirrorURL></interface></capability><capability><interface xsi:type="vs:ParamHTTP"><accessURL use="base">https://vizier.cds.unistra.fr/viz-bin/votable?-source=J/ApJ/818/120</accessURL><mirrorURL title="VizieR at IUCAA: Pune, India">https://vizier.iucaa.in/viz-bin/votable?-source=J/ApJ/818/120</mirrorURL><mirrorURL title="VizieR at SAAO: SAAO, South Africa">http://vizieridia.saao.ac.za/viz-bin/votable?-source=J/ApJ/818/120</mirrorURL><queryType>GET</queryType><resultType>text/xml+votable</resultType></interface></capability><capability standardID="ivo://ivoa.net/std/TAP#aux"><interface xsi:type="vs:ParamHTTP" role="std"><accessURL use="base">https://tapvizier.cds.unistra.fr/TAPVizieR/tap</accessURL></interface></capability><coverage><footprint ivo-id="ivo://ivoa.net/std/moc"/></coverage><tableset><schema><name>default</name><table><name>J/ApJ/818/120/table4</name><description>Adiabatic excitation energies and vibrational overlap integrals of the X^1^{Sigma}_g_^+^(v_m_,J_m_)-d^3^{Pi}_u_(v_n_,J_n_) transition</description><column><name>recno</name><description>Record number assigned by the VizieR team. Should Not be used for identification.</description><ucd>meta.record</ucd><dataType xsi:type="vs:VOTableType">int</dataType></column><column><name>vn</name><description>[0/20] Upper vibrational quantum number</description><ucd>phys.mol.qn</ucd><dataType xsi:type="vs:VOTableType">int</dataType></column><column><name>Jn</name><description>[1/24] Upper rotational quantum number</description><ucd>phys.mol.qn</ucd><dataType xsi:type="vs:VOTableType">int</dataType></column><column><name>vm</name><description>[0/1] Lower vibrational quantum number</description><ucd>phys.mol.qn</ucd><dataType xsi:type="vs:VOTableType">int</dataType></column><column><name>Jm</name><description>[0/20] Lower rotational quantum number</description><ucd>phys.mol.qn</ucd><dataType xsi:type="vs:VOTableType">int</dataType></column><column><name>Emn</name><description>[96234/133610] Adiabatic excitation energy</description><unit>cm**-1</unit><ucd>phys.atmol.excitation</ucd><dataType xsi:type="vs:VOTableType">double</dataType></column><column><name>&lt;Int&gt;</name><description>[-0.6/0.7] Vibrational overlap integral (1)</description><ucd>phys.mol.qn</ucd><dataType xsi:type="vs:VOTableType">double</dataType></column></table><table><name>J/ApJ/818/120/table5</name><description>Adiabatic energies, transition frequencies, transition probabilities, and Franck-Condon factors of the H_2_ d^3^{Pi}_u_-a^3^{Sigma}_g^+^ band system</description><column><name>recno</name><description>Record number assigned by the VizieR team. Should Not be used for identification.</description><ucd>meta.record</ucd><dataType xsi:type="vs:VOTableType">int</dataType></column><column><name>v1</name><description>[0/20] Upper vibrational quantum number</description><ucd>phys.mol.qn</ucd><dataType xsi:type="vs:VOTableType">int</dataType></column><column><name>J1</name><description>[0/21] Upper rotational quantum number</description><ucd>phys.mol.qn</ucd><dataType xsi:type="vs:VOTableType">int</dataType></column><column><name>v0</name><description>[0/20] Lower vibrational quantum number</description><ucd>phys.mol.qn</ucd><dataType xsi:type="vs:VOTableType">int</dataType></column><column><name>J0</name><description>[0/20] Lower rotational quantum number</description><ucd>phys.mol.qn</ucd><dataType xsi:type="vs:VOTableType">int</dataType></column><column><name>Energy</name><description>[111754.5/133834] Adiabatic energy of the upper level</description><unit>cm**-1</unit><ucd>phys.energy;phys.atmol.level</ucd><dataType xsi:type="vs:VOTableType">double</dataType></column><column><name>Freq</name><description>[-6620/38533.4] Transition frequency (1)</description><unit>cm**-1</unit><ucd>em.freq;phys.atmol.transition</ucd><dataType xsi:type="vs:VOTableType">double</dataType></column><column><name>A</name><description>Transition probability (2)</description><unit>s**-1</unit><ucd>phys.atmol.transProb</ucd><dataType xsi:type="vs:VOTableType">double</dataType></column><column><name>FCF</name><description>[0/0.96] Franck-Condon factor (3)</description><ucd>phys.atmol</ucd><dataType xsi:type="vs:VOTableType">double</dataType></column></table></schema></tableset></ri:Resource>