J/A+A/658/A103ivo://CDS.VizieR/J/A+A/658/A103doi:10.26093/cds/vizier.36580103CDSHoldship J.Viti S.2022-08-25T11:29:01Z2022-02-07T08:31:39ZCDS support team

CDS, Observatoire de Strasbourg, 11 rue de l'Universite, F-67000 Strasbourg, France

cds-question@unistra.frinterstellar-mediummolecular-physicsMolecular line emission is a powerful probe of the physical conditions of astrophysical objects but can be complex to model and it is often unclear which transitions would be the best targets for observers who wish to constrain a given parameter. We produce a list of molecular species for which the gas history can be ignored, removing a major modelling complexity. We then determine the best of these species to observe in order to constrain various physical parameters. We use a large set of chemical models with different chemical histories to determine which species have abundances at 1 MYr which are insensitive to the initial conditions. We then use radiative transfer modelling to produce the intensity of every transition of these molecules. We finally compute the mutual information between the physical parameters and all transitions and transition ratios in order to rank their usefulness in determining the value of a given parameter. We find 48 species which are insensitive to the chemical history of the gas, 23 of which have collisional data available. We produce a ranked list of all transitions and ratios of these species by their mutual information with various gas properties. We show mutual information is an adequate measure of how well a transition can constrain a physical parameter by recovering known probes and demonstrating random forest regression models become more accurate predictors when high scoring features are included. Therefore, this list can be used to select target transitions for observations in order to maximise knowledge about those physical parameters.2022A&A...658A.103Hhttps://cdsarc.cds.unistra.fr/viz-bin/cat/J/A+A/658/A103CatalogResearchIsServedByTAP VizieR generic servicehttps://cds.unistra.fr/vizier-org/licences_vizier.htmlhttps://vizier.cds.unistra.fr/viz-bin/VizieR-2?-source=J/A+A/658/A103https://vizier.iucaa.in/viz-bin/VizieR-2?-source=J/A+A/658/A103http://vizieridia.saao.ac.za/viz-bin/VizieR-2?-source=J/A+A/658/A103https://vizier.cds.unistra.fr/viz-bin/votable?-source=J/A+A/658/A103https://vizier.iucaa.in/viz-bin/votable?-source=J/A+A/658/A103http://vizieridia.saao.ac.za/viz-bin/votable?-source=J/A+A/658/A103GETtext/xml+votablehttps://tapvizier.cds.unistra.fr/TAPVizieR/tapdefaultJ/A+A/658/A103/filtersTable of mutual information scoresrecnoRecord number assigned by the VizieR team. Should Not be used for identification.meta.recordintFeatureName of feature combining species and transition frequencymeta.id;phys.molcharTargetName of physical parameter for which mutual information was calculated (1)meta.notecharMutualInfoMutual information score between the feature and the targetstat.fit.paramdoubleRatio[True /False] Flag for whether the feature is a transition ratiometa.codecharMol1Molecule to which the first (or only for non-ratios) transition belongsmeta.id;phys.molcharMol2Molecule to which the second transition belongs for ratios otherwise Nonemeta.id;phys.molcharMolsCombined list of molecules (Mol1-Mol2)meta.id;phys.molcharFreq1Rest frequency of first transitionGHzem.freq;phys.atmol.transitionfloatFreq2Rest frequency of second transitionGHzem.freq;phys.atmol.transitionfloat