J/A+A/445/361ivo://CDS.VizieR/J/A+A/445/361doi:10.26093/cds/vizier.34450361CDSAbgrall H.Roueff E.2017-07-10T06:38:09Z2008-05-13T21:56:31ZCDS support team

CDS, Observatoire de Strasbourg, 11 rue de l'Universite, F-67000 Strasbourg, France

cds-question@unistra.fratomic-physicsIn this paper, we derive the theoretical properties of rovibrational levels belonging to excited B, C, B', and D electronic states of HD. We compute the eigenvalues and eigenfunctions of the nuclear coupled Schroedinger equations using ab initio electronic molecular properties available in the literature. Transition wavenumbers and spontaneous emission probabilities are calculated for all transitions belonging to B-X, C-X, B'-X, and D-X electronic band systems of HD when the upper rotational quantum number is below or equal to 10. We compare our results with available experimental values: the accuracy in the wavenumbers is on the order of 3 reciprocal centimetres, whereas the intensity properties are satisfactorily reproduced. The origin of the remaining discrepancies is analyzed.2006A&A...445..361Ahttps://cdsarc.cds.unistra.fr/viz-bin/cat/J/A+A/445/361CatalogResearchIsServedByTAP VizieR generic servicerelated-toJ/A+AS/117/561 : Rovibrational dipole matrix elements for CO (Hure+ 1996)J/A+AS/141/297 : H_2_ total transition probability (Abgrall+, 2000)https://cds.unistra.fr/vizier-org/licences_vizier.htmlhttps://vizier.cds.unistra.fr/viz-bin/VizieR-2?-source=J/A+A/445/361https://vizier.iucaa.in/viz-bin/VizieR-2?-source=J/A+A/445/361http://vizieridia.saao.ac.za/viz-bin/VizieR-2?-source=J/A+A/445/361https://vizier.cds.unistra.fr/viz-bin/votable?-source=J/A+A/445/361https://vizier.iucaa.in/viz-bin/votable?-source=J/A+A/445/361http://vizieridia.saao.ac.za/viz-bin/votable?-source=J/A+A/445/361GETtext/xml+votablehttps://tapvizier.cds.unistra.fr/TAPVizieR/tapUVdefaultJ/A+A/445/361/levelsLevels of the electronic states of the HD moleculevVibrational quantum numberphys.atmol.qn;phys.mol.vibrationintrecnoRecord number assigned by the VizieR team. Should Not be used for identification.meta.recordintstateSimbad column added by the CDSphys.atmol.levelcharnuOrder of e-parity vibrational levelsphys.atmol.qnintJRotational quantum numberphys.atmol.qn;phys.mol.rotationintrho(B)Fraction of the B.O. state B (cf eq.(2)) (2)phys.atmoldoublerho(C)Fraction of the B.O. state C (cf eq.(2)) (2)phys.atmoldoublerho(B')Fraction of the B.O. state B' (cf eq.(2)) (2)phys.atmoldoublerho(D)Fraction of the B.O. state D (cf eq.(2)) (2)phys.atmoldoubleE(v,J)Term value of the state (x,v,J) where x is B in table5, C+ in table6, D+ in table7, C- in table8, C- in table9, D- in table10.cm**-1phys.energy;phys.atmol.leveldoubleAtTotal emission probability towards Xs**-1phys.atmol.transProbdoubleAcTotal dissociation probability towards the continuum of Xs**-1phys.atmol.transProbdoubleJ/A+A/445/361/transTransitions in the HD moleculerecnoRecord number assigned by the VizieR team. Should Not be used for identification.meta.recordintstateSimbad column added by the CDSphys.atmol.levelcharv1Vibrational quantum number of upper statephys.atmol.qnintJ1Rotational quantum number of upper statephys.atmol.qnintv0Vibrational quantum number of lower statephys.atmol.qnintJ0Rotational quantum number of lower statephys.atmol.qnintASpontaneous emission transition probability: (B - X) for table11, (C+ - X) for table12, (B' - X) for table13, (D+ - X) for table14 and (C- - X) for table15, (D- - X) for table16s**-1phys.atmol.transProbdoubleEtrTransition energycm**-1phys.energy;phys.atmol.transitiondoubleo-c? Difference between the observed and calculated transition energycm**-1stat.fit.residualdoublenullablemnCode about technique and determination (G1)meta.codeint